This unique text discusses the solution self-assembly of block copolymers and covers all aspects from basic physical chemistry to applications in soft nanotechnology. It addresses the principles of self-assembly in both dilute and concentrated solutions (e.g., micellization and mesophase formation); polyelectrolyte block copolymers and their underlying physical chemistry; and adsorption at liquid and solid interfaces. The final applications chapter focuses on several important new concepts, rather than providing an account of specific commercial applications.

From the Preface: “I was inspired to write this book by developments in the field of block copolymer self-assembly in solution which have not been discussed and summarized in the form of a single convenient text...Recent advances have been stimulated in part by new synthetic methodologies (living polymerizations in particular) that have enabled the preparation of new materials with novel self-assembling structures, functionality and responsiveness...”

Target Audience: Researchers in polymer science, industrial scientists involved in the polymer and coatings industries, and scientists concierned with soft matter self-assembly and self-organizing polymers.

Table of Contents:

Introduction

Neutral Block Copolymers in Dilute Solution

Concentrated Solutions

Polyelectrolyte Block Copolymers

Adsorption

Applications

Index